7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. 26 Sep 2016 European chemical experts have recommended that the European Commission continues to allow carcinogen chromium trioxide for critical uses, but with strict conditions attached. 2, Dir 2004/37/EC (CMD), as amended by Dir 2019/130/EU, 31 Jan 2019, EU. Harmonisation is based on the substance’s physical, toxicological and eco-toxicological hazard assessment. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. Close Find out more on how we use cookies. ECHA recommends authorising critical continued uses of chromium trioxide under strict conditions ECHA’s scientific committees adopted a total of 61 positive draft or final opinions at their September meetings. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. The NTP have provisionally concluded that these studies both provide 'clear evidence' of carcinogenicity. Up to 10 Jan 2018, the list includes more than 43Substances of Very High Concern (SVHC) such as Trichloroethylene (CAS 79-01-6), Chromium trioxide(CAS 1333-82-0), Bis(2-ethylhexyl) phthalate (DEHP), and Diisobutyl phthalate (DIBP), etc. Release to the environment of this substance can occur from industrial use: formulation in materials. This section highlights four regulatory activities or outcomes under REACH – Registration, Evaluation, Authorisation and Restriction of Chemicals – Regulation (EC) No 1907/2006: Please note: The identification of relevant regulatory activities and outcomes is done automatically and without manual verification. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is fatal if inhaled, is toxic if swallowed, is toxic in contact with skin, causes severe skin burns and eye damage, may cause genetic defects, may cause cancer, causes damage to organs through prolonged or repeated exposure, is very toxic to aquatic life, is very toxic to aquatic life with long lasting effects, may cause fire or explosion (strong oxidiser), is suspected of damaging fertility, may cause an allergic skin reaction and may cause allergy or asthma symptoms or breathing difficulties if inhaled. What is the Classification and Labelling Inventory? found on the European Chemical Agency’s (ECHA) Authorisation Applications website There are several upstream applications for authorisation that cover generic uses of chromium trioxide, and specific aerospace and defence uses of chromium trioxide and other chromates (see also Appendix A of this letter for a summary of some relevant This substance is used in the following products: adsorbents and laboratory chemicals. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. According to the EU REACH legislation chromium trioxide was listed as a substance of high concern, and thus was banned by 21 September 2017 (“sunset date”) unless its further use would be authorized by the EU Commission. The ECHA website is temporarily down for maintenance. Chromium trioxide has various toxicological properties, such as acute and chronic toxicity, corrosivity as well as skin and respiratory sensitisation. Substances for which an agreed set of classification and labelling data has been agreed at EU level by Member States. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance is fatal in contact with skin, is suspected of damaging fertility or the unborn child and may cause respiratory irritation. The EC Number is the numerical identifier for substances in the EC Inventory. This site is not fully supported in Internet Explorer 7 (and earlier versions). This compound is a dark-purple solid under anhydrous conditions, bright orange when wet and which dissolves in water concomitant with hydrolysis. REACH Chromium trioxide The Committee's opinions evaluate the risks of continuing use, recommending strict conditions where necessary to limit exposure to workers. A slight increase in the incidence of respiratory tract (lung and pharynx) tumours was seen at the highest exposure concentration in rats exposed to aerosols of sodium dichromate (Glaser et al, 1986). Similar findings of marginally increased tumour incidences were reported in one of two rat studies performed using intrabronchial implantation of pellets containing chromium (VI) trioxide (Laskin et al, 1970; Levy et al, 1986). Tool showing an overview of substances in various key regulatory processes that authorities are working on. Chromium trioxide is mainly used in metal finishing/surface treatment and as catalysts. The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). These mainly concern the carcinogen chromium trioxide. A substance may have its use restricted to certain articles or products and therefore not all the examples may apply to the specific substance. The EU Ecolabel may not be awarded to substances or mixtures classified as such. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the, Substance of very high concern (SVHC) and included in the, Substance of very high concern requiring authorisation before it is used (. Information on Chromium Trioxide Authorization for the rotogravure industry is available from ERA or from Kaspar Walter. Close Find out more on how we use cookies. Yara France Diarsenic trioxide 4-CSR-ES ECHA documentation – Diarsenic trioxide 4 Lead sulfochromate yellow & Lead chromate molybdate sulphate red C(2016)5644 OJ C337, 14.09.2016, p. 3 DCC Maastricht B.V. Lead sulfochromate yellow 1-CSR-ES-use 1 Lead chromate molybdate sulfate red 1-CSR-ES-use 1 Lead sulfochromate yellow 1-CSR-ES-use 2 BPR regulation aims to improve the functioning of the biocidal products market in the EU, while ensuring a high level of protection for humans and the environment. This site is not fully supported in Internet Explorer 7 (and earlier versions). The examples provided are generic examples and may not apply to the specific substance you are viewing. 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. Dangerous Goods List (ADN, Chap. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. 3. ECHA has no public registered data on the types of manufacture using this substance. Chromium trioxide: 215-607-8 1333-82-0 13/01/2021: DOURECA - Produtos Plásticos, Lda. Release to the environment of this substance can occur from industrial use: formulation in materials. Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice. Hazardous Substances - Art. This list contains biological and chemical agents, in accordance with Art. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). Substances listed in the EINECS, ELINCS, or NLP inventories. Chromium trioxide is an inorganic compound with the formula CrO3. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Please click the picture below to download the latest authorization list. The information is aggregated from the data coming from REACH substance registrations provided by industry. Welcome to the ECHA website. This information has not been reviewed or verified by the Agency or any other authority. Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). Search results for chromium trioxide at Sigma-Aldrich. For readability purpose, only non-confidential use descriptors occurring in more than 5% of total occurrences are displayed. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. This website uses cookies to ensure you get the best experience on our websites. No change to the classification is proposed. The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. However the reduction of Cr (VI) to Cr (III) in the body (saliva, gastric juice, erythrocye) may explain the lack of carcinogenicity of Cr (VI) at sites distant from the site of exposure. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. Note that this list is not exhaustive. 6(6), Reg. Substances for which authorisation is required to be allowed to use the substance. Substances may have impurities and additives that lead to different classifications. EU. Substances Rendering Goods Ineligible for EU Ecolabel, Art. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. More information about Classification and Labelling is available in the Regulations section of ECHA website. It is the responsibility of the substance manufacturers and importers to consult official publications, e.g. Chromium trioxide EC Number: 215-607-8 EC Name: Chromium trioxide CAS Number: 1333-82-0 Molecular formula: CrO3 IUPAC Name: trioxochromium Welcome to the ECHA website. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. the electronic edition of the Official Journal of the European Union should be consulted. Chromium (VI) and chromium (III) are the most stable oxidation states of chromium at the redox potential (Eh) and pH range of natural waters. It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. ECHA has no public registered data indicating whether or into which articles the substance might have been processed. Submit your comments until 9 October 2019. Regulamentul CLP asigură comunicarea clară a pericolelor pe care le prezintă substanțele chimice către lucrătorii și consumatorii din Uniunea Europeană, prin clasificarea și etichetarea substanțelor chimice. InfoCards are generated automatically based on the data available at the time of generation. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. This substance is used in the following products: adsorbents and laboratory chemicals. Chromium trioxide is a powerful … Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). The EC or list number is the primary substance identifier used by ECHA. Dangerous Goods List (RID, Chap. A clear increase in the incidence of lung tumours was seen in a study using intratracheal instillation of sodium dichromate (Steinhoff et al, 1985). The date of the last update corresponds to the publication date of the InfoCard and not necessarily to the date in which the update occurred in the source data. 66/2010/EC, L 27/1, 30 Jan 2010 (T. 3 of Anx VI to CLP; Candidate List of SVHCs), EU. Please upgrade your Internet Explorer to a newer version. InfoCards are updated when new information is available. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. It covers their hazardous properties, classification and labelling, and information on how to use them safely. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. The source of the information is mentioned in the introductory sentence of the hazard statements. In accordance with the REACH Regulation, applications to authorise the use of chemicals are first examined by ECHA’s Committees for Risk Assessment and Socio-economic Analysis. the electronic edition of the Official Journal of the European Union. restriction on "Lead and its compounds"). This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. The type of uses and classifications may vary between different submissions to ECHA and for a full understanding it is recommended to consult the source data. Two soils were used in the experiment. This classification is based on the results of studies in animals, the genotoxicity of chromium (VI) trioxide, and findings of increased lung tumours in occupationally exposed humans. This is unique source of information on the chemicals manufactured and imported in Europe. MOTION FOR A RESOLUTION. Chromium (VI) trioxide is listed on Annex I of Directive 67/548/EEC and is classified as a Category 1 carcinogen (R45: 'May cause cancer'). Other release to the environment of this substance is likely to occur from: indoor use as reactive substance. Authorization following the outstanding CrO 3 usage ban would require downstream users, to which K.Walter’s customers belong, to report their use of chromium trioxide to the ECHA. Employers are obligated to minimize worker exposure to these agents as far as possible, and must arrange for medical surveillance of workers exposed to these substances. This website uses cookies to ensure you get the best experience on our websites. Information on precautionary measures and the safe use is submitted by the registrant of a substance and the registrant is solely responsible for its accuracy and completeness. This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. This information is only displayed if the substance is well–defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. This is a non-exhaustive list of substances based on the Article 2 carcinogen and mutagen (CM) definitions and Annex I of Directive 2004/37/EC. If generated, an InChI string will also be generated and made available for searching. This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. This classification is based on the results of studies in animals, the genotoxicity of chromium (VI) trioxide, and findings of increased lung tumours in … The EU RAR discussion of the carcinogenicity of chromium (VI) compounds is shown below; this review discusses the results of the inhalation carcinogenicity studies performed with chromium (VI) trioxide, as well as studies with other chromium (VI) salts and incorporates the studies previously reviewed by the HSE and IOH. This is only a partial list; employers are obliged to prevent the exposure of these workers to any agents that may cause adverse health effect for either mother or child. This would have to happen within three months after a company received a delivery of CrO3 with the new safety data sheet, including authorization number. Substances to be considered for potential authorisation at EU level. One soil had a pH of 5.2 and a clay and humus content of 36.1% and 7.0% respectively, and the second had a pH of 6.9 and a clay and humus content of 54.3% and 3.4% respectively. ECHA has no public registered data indicating whether or in which chemical products the substance might be used. In these cases, Infocards may not identify all substances in the group.Therefore it does not represent official and legally–binding information. the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. More information about the EC Inventory can be found here. Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. The prevalent species present at equilibrium depends both on the pH and Eh of a given system (see figure on page 72 of the EU RAR). Please try again later. If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. The findings in these studies were associated with chronic irritation and corrosion of the respiratory tract. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled. This database contains the ADN's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. pursuant to Rule 112(2) and (3) of the Rules of Procedure. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC. Water-soluble hexavelent chromium compounds are genotoxic in vitro and in vivo. This substance has not been registered under the REACH Regulation, therefore as yet ECHA has not received any data about this substance from registration dossiers. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). 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